ABS Fudge

Many months ago I put some HIPS, ABS and PLA in a jar of limonene. The HIPS dissolved completely fairly quickly and the ABS and PLA were seeming unaffected. I then forgot about it until yesterday.

The PLA is still completely unaffected but the ABS has become soft like fudge.

I assume that given long enough the limonene removes the styrene content from the ABS.

It looks like it is feasible to use HIPS as a support material for PLA and then remove it with limonene. Limonene isn't cheap though and it remains to be seen how much HIPS it can dissolve before it becomes too dilute.

More trifurcated PLA

I repeated the PLA in acetone experiment with red PLA and pure acetone. Same result, trifurcation after a few minutes:

Here is what happens to an object:

These were identical PLA clothes-pegs, one was dipped in acetone for a few minutes.  It fell apart when I tried to pick it out with tongs.

A bit of Googling reveals acetone causes PLA (which is normally amorphous) to become crystalline. That explains why it loses its transparency I think. It also becomes rubbery and crumbly.

Not a very useful result, but it does show that acetone would not be any good for cleaning out a hot end filled with PLA. Also I think people have suggested you could use ABS as support for PLA and dissolve it out with acetone but that plainly will not work either. The opposite works, dissolving the PLA with an alkali.

Peeled PLA

I have read conflicting forum posts as to whether acetone dissolves PLA or not, so I dropped a piece into a jar of acetone for an hour or so. The effect was truly bizarre:

It split into three strands a bit like peeling a banana. It was clear PLA but the acetone was polluted with ABS, which is why it turned white I think. Whereas it is normally transparent and brittle, it has become translucent soft and flexible. When I opened the jar it was under pressure so I think it evolved some gas.

So acetone doesn't dissolve PLA, but it appears to trifurcate it!

Not a very scientific experiment as I should have done it with pure acetone, but interesting never the less.