The first problem was easy enough to diagnose. Since I had rebuilt and rewired the circuit it had to be the thermistor itself. After removing it, I could see the underside was looking a bit toasted. I don't think it was designed for use up to 250°C. The insulation on the wire was not up to it and I suspect it was soldered to the actual device, and that the solder melted. There seems to be some solder on the brass nozzle now where it was mounted.
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The remedy was easy: I just replaced it with the recommended glass bead thermistor which had arrived from back order in the meantime. It is rated to 300°C. Its characteristics are different so I had to change my resistor values, but I had anticipated that by mounting them on the connector rather than the board.
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